-
theoretical calculations an O,O-
dicationic intermediate (a superelectrophile) is
favored comparing to the N,O
dicationic intermediate. For
preparative purposes...
- Ge(II)
dicationic complexes refer to
coordination compounds of
germanium with a +2
formal oxidation state, and a +2
charge on the
overall complex. In some...
- substrates, respectively,
though in rare cases,
cations leaving from a
dicationic substrate are also known. A species'
ability to
serve as a
leaving group...
- Acid-base
reaction of a
dicationic glycinamide complex (L =
arbitrary ligand)....
- methyl-derivative:
Formation of
aminothiazoles and
aminothiadiazoles through dicationic disulfides".
Dalton Trans. 43 (12): 4790–4806. doi:10.1039/C3DT53302F...
- "Prototype Pictet−Spengler
Reactions Catalyzed by Superacids.
Involvement of
Dicationic Superelectrophiles". J. Org. Chem. 64 (2): 611–617. doi:10.1021/jo982019e...
-
methyl (see paraquat), long
chain alkyl, and benzyl. Viologens, in
their dicationic form,
typically undergo two one-electron reductions. The
first reduction...
-
unhindered or
strained alkenes to the
corresponding alkenes and alkanes. The
dicationic form, H−N+≡N+−H (diazynediium,
diprotonated dinitrogen), is calculated...
-
fulfilling the
IUPAC definition of antiaromaticity. Pentalene’s
dianionic and
dicationic states are aromatic, as they
follow Hückel’s 4n +2 π-electron rule. Like...
-
Sydney Thesis A
theoretical approach to hemi-bonded
systems and
their dicationic analogues (1988)
Doctoral advisor Leo
Radom Other academic
advisors John...
