- the
University of Georgia's
Gregory Robinson presented the
first neutral diborene (RHB=BHR): Each
boron atom has an
attached proton and is
coordinated to...
-
double bond character,
explaining the high
reactivity of
these compounds.
Diborenes have
potential applications in
materials science,
catalysis and sustainable...
- high-yield
synthesis of
neutral compounds containing boron-boron
double bonds (
diborenes). In 2016
Braunschweig isolated the
first compounds of
beryllium in the...
- dimer—a
diborene. An (NHC)BBr3
adduct was
reduced to
generate a
probable (NHC)B-H
intermediate that
subsequently dimerized to form the
diborene. A similar...
- (n=2) O
oxygen (n=2) Si
silicon (n=3) P
phosphorus (n=3) S
sulfur (n=3) B
diborenes alkylideneboranes aminoboranylidenes, rare oxoboranes, rare,
rapid oligomerization...
- bond, but with NHC ligands, the
third excited state yields a
triple bond.
Diborene Zhou, M; Tsumori, N; Li, Z; Fan, K; Andrews, L; Xu, Q (2002). "OCBBCO:...
- "Planar, Twisted, and Trans-Bent:
Conformational Flexibility of
Neutral Diborenes".
Journal of the
American Chemical Society. 130 (11): 3298–3299. doi:10...
- {\displaystyle 4/3} , the
average B-B bond
length of 1.62 Å is
closer to
those of
diborene (R-B=B-R)
radical cations than B−B
single bonds of
roughly 1.75 Å....
- form B 2 Br 2 ( IDip ) 2 {\displaystyle {\ce {B2Br2(IDip)2}}} , a
stable diborene, and
could ultimately be
reduced further to form B 2 ( IDip ) 2 {\displaystyle...
