Definition of Diazoacetate. Meaning of Diazoacetate. Synonyms of Diazoacetate

- Ethyl diazoacetate (N=N=CHC(O)OC2H5) is a diazo compound and a reagent in organic chemistry. It was discovered by Theodor Curtius in 1883. The compound...
- itself, are explosive. A commercially relevant diazo compound is ethyl diazoacetate (N2CHCOOEt). A group of isomeric compounds with only few similar properties...
- 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in...
- Buchner ring enlargement, starts with the reaction of benzene with ethyl diazoacetate to give the corresponding norcaradiene ethyl ester, which then undergoes...
- postulated by Eduard Buchner in 1903 in cyclopropanation studies of ethyl diazoacetate with toluene. In 1912 Hermann Staudinger also converted alkenes to cyclopropanes...
- 2-dioxaphosphorinane forms a phosphite ester. (ii) Metal carbene addition (from ethyl diazoacetate and ClFeTPP) forms an ylide. (iii) A rearrangement reaction (in blue)...
- was reported by St. Pfau and Plattner starting from indane and ethyl diazoacetate. An efficient one-pot route entails annulation of cyclopentadiene with...
- tetraacetate is found to be especially effective. In a typical reaction ethyl diazoacetate (a well-known carbene precursor) and dirhodium tetraacetate react with...
- of carbenes to alkynes. In the presence of a copper catalyst, ethyl diazoacetate reacts with acetylenes to give cyclopropenes. 1,2-Dimethylcyclopropene-3-carboxylate...
- (2011-05-13). "Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO 2". Science. 332 (6031): 835–838. Bibcode:2011Sci...