-
Aldehyde deformylating oxygenases (ADO) (EC 4.1.99.5) are a
family of
enzymes which catalyze the
oxygenation of
medium and long
chain aldehydes to alkanes...
- (EC 4.1.2.44, 2,3-dihydro-2,3-dihydroxybenzoyl-CoA lyase/hydrolase (
deformylating), BoxC,
dihydrodiol transforming enzyme, benzoyl-CoA
oxidation component...
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group and loss of the beta and
gamma phosphate groups. The
molecule is
deformylated by 2-amino-5-formylamino-6-ribosylaminopyrimidin-4(3H)-one 5'-monophosphate...
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Reduction of the Diferric-Peroxyhemiacetal
Intermediate in Aldehyde-
Deformylating Oxygenase by a
Cyanobacterial Ferredoxin:
Evidence for a Free-Radical...
-
sequence of two
enzymatic reactions. First,
peptide deformylase (PDF)
deformylates it,
converting the
residue back to a
normal methionine. Then methionine...
- N-formyl-4-amino-5-aminomethyl-2-methylpyrimidine is
transported into the cell and
deformylated by the
amidohydrolase ylmB and
hydrolyzed to 5-aminoimidazole ribotide...
- was
observed that SeCYP125
favors formation of
oxidized products vs
deformylated products when
reacted with cholesterol-26-aldehyde,
indicating that increased...
-
cyclopentylidene was
removed and a diol was produced. This diol was then cleaved,
deformylated, and
treated with
excess (formylmethylene)triphenylphosphorane, resulting...