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Decaborane, also
called decaborane(14), is the
inorganic compound with the
chemical formula B10H14. It is
classified as a
borane and more specifically...
- formaldehyde. For example,
monocarbadodecaborate ([CB11H12]−) is
produced from
decaborane and formaldehyde,
followed by
addition of
borane dimethylsulfide. Monocarboranes...
- dopant, catalyst, used in
organic synthesis; also borane,
pentaborane and
decaborane arsine: used for
doping semiconductors stibine: used in semiconductor...
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Decaborane is a
powerfully toxic cluster compound of boron...
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diborane gives boron hydride clusters, such as pentaborane(9) B5H9 and
decaborane B10H14.: 164, 170, 173 A
large number of
anionic boron hydrides are also...
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Cyanogen iodide Cyanophos Cyanuric fluoride Cycloheximide Cyclohexylamine Decaborane(14)
Demeton Demeton-S-methyl
Dialifor Diborane Dichloroethyl ether...
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clusters were
determined beginning in 1948 with the
characterization of
decaborane.
William Lipscomb was
awarded the
Nobel Prize in
Chemistry in 1976 for...
-
addition of
acetylenes to
decaborane(14).
Modern syntheses involve two stages, the
first involving generation of an
adduct of
decaborane: B10H14 + 2 SEt2 → B10H12(SEt2)2...
- (B 2H 6) at ca. 200 °C.
Products include the
clusters pentaborane and
decaborane.
These pyrolyses involve not only
cracking (to give H 2), but also recondensation...
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specialized equipment. The
starting material is
commercially available decaborane(14), a
highly toxic substance. The most well-studied
carborane acid H(CHB...
