- one
organyl group and the
metal fragment across the
multiple bond (
carboalumination). This
process can
proceed in a
purely thermal manner or in the presence...
- Carboboration. The
carboalumination reaction is most
commonly catalyzed by
zirconocene dichloride (or
related catalyst). Some
carboaluminations are performed...
-
butane via
reductive elimination.
Zirconocene dichloride catalyzes the
carboalumination of
alkynes by
trimethylaluminium to give a (alkenyl)dimethylalane,...
-
species that are
useful in
organic synthesis in a
reaction known as
carboalumination. As for
other "electron-deficient" compounds,
trimethylaluminium gives...
- Ei-ichi (2010). "Discovery of ZACA
reaction − Zr-catalyzed
asymmetric carboalumination of alkenes". Arkivoc. 2011 (8).
Arkat USA: 34-45. doi:10.3998/ark.5550190...
-
aluminium to an
electrophilic atom.
Stereospecific hydroalumination,
carboalumination, and
terminal alkyne metalation are
useful methods for
generation of...
-
Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed
Asymmetric Carboalumination and Pd-Catalyzed Cross-Coupling of Organozincs". Org. Lett. 6 (19):...
-
Route to
Carotenoids and
Related Natural Products via Zr-Catalyzed
Carboalumination and Pd- and Zn-Catalyzed
Cross Coupling". Org. Lett. 3 (5): 719–722...
- Muller, Robert; Kaupp, Martin; Demeshko, Serhiy; Kempe,
Rhett (2009). "
Carboalumination of a chromium–chromium
quintuple bond".
Nature Chemistry. 1 (4): 322–325...
- Enders,
Markus (2009). "Organochromium
complexes as
catalysts for the
carboalumination of
unactivated terminal olefins".
Dalton Transactions (25): 4875–4877...
