- atom in a carbene. For this
reason stable borylenes are more
uncommon than
stable carbenes. Some
borylenes such as
boron monofluoride (BF) and
boron monohydride...
- hydride,
typically named -ane or -ine.
borenium cations, R2B+ (protonated
borylenes a.k.a. boranylidenes)
carbenium cations, R3C+ (protonated carbenes) have...
-
gallium species which may have a lone pair,
analogous to NHC's or
terminal borylenes. They are
compounds of
academic interest because of
their distinctive...
- the
field of
transition metal-boron
multiple bonding (transition
metal borylenes), the
synthesis of the
first stable compounds containing boron-boron and...
-
corresponding to the
notional boryl anion R2B−.
Related ligands are
borylenes (M–B(R)–M).
Strong bases do not
deprotonate boranes R2BH.
Instead these...
-
molecule of
dinitrogen is
bound by two
transient Lewis-base-stabilized
borylene species. The
resulting dianion was
subsequently oxidized to a
neutral compound...
-
centered molecules (e.g., low
valent main
group metal Ca,
dicoordinate borylene,
boron radical, carbene, etc.).
Dinitrogen fixation is
essential for human...
-
metal in
diethyl ether to
yield the reactive,
highly electron-deficient
borylene intermediate,
which is able to
insert into the
strong C–C σ bond to form...
-
fluorine atoms,
compared with
boron trifluoride. It can also be
called a
borylene, as it
contains boron with two
unshared electrons. BF is isoelectronic...
- Rian D Dewhurst;
Viktoria H
Gessner (12
February 2013). "Transition
metal borylene complexes".
Chemical Society Reviews. 42 (8): 3197–3208. doi:10.1039/C3CS35510A...
