Definition of Enolate. Meaning of Enolate. Synonyms of Enolate

Here you will find one or more explanations in English for the word Enolate. Also in the bottom left of the page several parts of wikipedia pages related to the word Enolate and, of course, Enolate synonyms and on the right images related to the word Enolate.

Definition of Enolate

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Phenolate
Phenolate Phe"no*late, n. [Phenol + -ate.] (Chem.) A compound of phenol analogous to a salt.

Meaning of Enolate from wikipedia

- In organic chemistry, enolates are organic anions derived from the deprotonation of carbonyl (RR'C=O) compounds. Rarely isolated, they are widely used...
- the stepwise process, the result is an anion termed an enolate (see images at right). The enolate structures shown are schematic; a more modern representation...
- enantiomer. Lithium enolates are formed through deprotonation of a C−H bond α to the carbonyl group by an organolithium species. Lithium enolates are widely used...
- quantitatively form the enolate of one partner, and the forward aldol reaction must be significantly faster than the transfer of the enolate from one partner...
- case mediated by the enolate or the proton source. In the deprotonation of an unsymmetrical ketone, the kinetic product is the enolate resulting from removal...
- enolizable (have an α-proton and be able to undergo deprotonation to form the enolate anion). There are a number of different combinations of enolizable and...
- In its usual form, it involves the nucleophilic addition of a ketone enolate to an aldehyde to form a β-hydroxy ketone, or aldol (aldehyde + alcohol)...
- or ketones. Aldol addition or aldolization refers to the addition of an enolate or enolation as a nucleophile to a carbonyl moiety as an electrophile....
- cannot form an enolate, and the benzaldehyde is much more electrophilic than any unenolized acetophenone in solution. Therefore, the enolate formed from...
- of an α hydrogen atom by an electrophile, E, through either an enol or enolate ion intermediate. Because their double bonds are electron rich, enols behave...