- increased. At the same time, π-
backbonding lowers the νCN.
Depending on the
balance of σ-bonding
versus π-
backbonding, the νCN can
either be
raised (for...
- (PhD) Known for See list
Alpha sheet Ancestral sequence reconstruction Backbonding Beta
sheet Bond
order Breath gas
analysis Coiled coil Corey-Pauling rules...
- in
coordination complexes is metal-to-ligand π bonding, also
called π
backbonding. It
occurs when the
LUMOs (lowest
unoccupied molecular orbitals) of the...
- than expected.
Aromatic interaction Delta bond
Molecular geometry Pi
backbonding Pi
interaction Streitwieser, Andrew; Heath****,
Clayton H.; Kosower,...
- carbon–oxygen bond, and
inversely correlated with the
strength of the π-
backbonding between the
metal and the carbon. The π-basicity of the
metal center...
-
making certain carbon atom or
other atom positions.
Mesomeric effect Pi
backbonding Baker–Nathan effect: the
observed order in electron-releasing
basic substituents...
-
electron loss of
silicon to the more
electronegative halogen atoms by pi
backbonding from the
filled pπ
orbitals on the
halogen atoms to the
empty dπ orbitals...
-
inorganic polymer, even
though they have
extensive organic substituents.
Their backbond is
composed of
alternating silicon and
oxygen atoms, i.e. Si-O-Si-O......
- π* and d
orbitals of
suitable energy,
there is the
possibility of pi
backbonding, and the
ligands may be π acceptors. This
addition to the
bonding scheme...
- of the
other lanthanides, as they all
share an
inability to
undergo π
backbonding. They are thus
mostly restricted to the
mostly ionic cyclopentadienides...